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1 материалы mpl сырьевые бумажного производства
Словарь по целлюлозно-бумажному производству > материалы mpl сырьевые бумажного производства
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2 Cai Lun (Tsai Lun)
SUBJECT AREA: Paper and printing[br]b. c.57 AD Chinad. c.121 AD China[br]Chinese Director of Imperial Workshops who is usually credited with the invention of paper.[br]He was a confidential secretary to the Emperor. He became Director of the Imperial Workshops and he is said to have invented, or sponsored the invention of, paper around the year 105 AD. Recent studies, however, suggest that paper was already known in China two centuries earlier. The method of making it has hardly varied in principle since that time. The raw materials, then usually old fishing nets and clothing rags, were boiled with water, to which alkali in the form of wood ash was sometimes added. The resulting pulp was then beaten in a stone mortar with a stone or a wooden mallet. The pulp was then mixed and stirred with a large amount of water, and a sieve or mould (formed on a wooden frame carrying a mat of thin reeds sewn together) was dipped into it and was shaken to help the fibres in the layer of pulp to interlock and thus form a sheet of paper. The rest of the process consisted, then as now, of getting rid of the water: the sheets of paper were dried and bleached by leaving them to lie in the sun.Some of China's many inventions were achieved independently in Western Europe, but it seems that Europe's knowledge of papermaking stems from the Chinese. It was not until the eighth century that it passed into the Islamic world and so, first by contact with the Moors in Spain in the twelfth century, into Western Europe.Cai Lun was later made a marquis. Further promotion followed when he was regarded as the god of papermaking.[br]Further ReadingJ.Needham, 1985, Science and Civilisation in China, Cambridge: Cambridge University Press, Vol. V (1): Clerks and Craftsmen in China and the West, 1970.LRD -
3 Mitscherlich, Alexander
SUBJECT AREA: Paper and printing[br]b. 28 May 1836 Berlin, Germanyd. 31 May 1918 Oberstdorf, Germany[br]German inventor of sulphite wood pulp for papermaking.[br]Mitscherlich had an impeccable scientific background; his father was the celebrated chemist Eilhardt Mitscherlich, discoverer of the law of isomorphism, and his godfather was Alexander von Humboldt. At first his progress at school failed to live up to this auspicious beginning and his father would only sanction higher studies if he first qualified as a teacher so as to assure a means of livelihood. Alexander rose to the occasion and went on to gain his doctorate at the age of 25 in the field of mineralogical chemistry. He worked for a few years as Assistant to the distinguished chemists Wöhler in Göttingen and Wurtz in Paris. On his father's death in 1863, he succeeded him as teacher of chemistry in the University of Berlin. In 1868 he accepted a post in the newly established Forest Academy in Hannoversch-Munden, teaching chemistry, physics and geology. The post offered little financial advantage, but it left him more time for research. It was there that he invented the process for producing sulphite wood pulp.The paper industry was seeking new raw materials. Since the 1840s pulp had been produced mechanically from wood, but it was unsuitable for making fine papers. From the mid-1860s several chemists began tackling the problem of separating the cellulose fibres from the other constituents of wood by chemical means. The American Benjamin C.Tilghman was granted patents in several countries for the treatment of wood with acid or bisulphite. Carl Daniel Ekman in Sweden and Karl Kellner in Austria also made sulphite pulp, but the credit for devising the process that came into general use belongs to Mitscherlich. His brother Oskar came to him at the Academy with plans for producing pulp by the action of soda, but the results were inferior, so Mitscherlich substituted calcium bisulphite and in the laboratory obtained good results. To extend this to a large-scale process, he was forced to set up his own mill, where he devised the characteristic towers for making the calcium bisulphite, in which water trickling down through packed lime met a rising current of sulphur dioxide. He was granted a patent in Luxembourg in 1874 and a German one four years later. The sulphite process did not make him rich, for there was considerable opposition to it; government objected to the smell of sulphur dioxide, forestry authorities were anxious about the inroads that might be made into the forests and his patents were contested. In 1883, with the support of an inheritance from his mother, Mitscherlich resigned his post at the Academy to devote more time to promoting his invention. In 1897 he at last succeeded in settling the patent disputes and achieving recognition as the inventor of sulphite pulp. Without this raw material, the paper industry could never have satisfied the insatiable appetite of the newspaper presses.[br]Further ReadingH.Voorn "Alexander Mitscherlich, inventor of sulphite wood pulp", Paper Maker 23(1): 41–4.LRDBiographical history of technology > Mitscherlich, Alexander
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4 Cross, Charles Frederick
[br]b. 11 December 1855 Brentwood, Middlesex, Englandd. 15 April 1935 Hove, England[br]English chemist who contributed to the development of viscose rayon from cellulose.[br]Cross was educated at the universities of London, Zurich and Manchester. It was at Owens College, Manchester, that Cross first met E.J. Bevan and where these two first worked together on the nature of cellulose. After gaining some industrial experience, Cross joined Bevan to set up a partnership in London as analytical and consulting chemists, specializing in the chemistry and technology of cellulose and lignin. They were at the Jodrell laboratory, Kew Gardens, for a time and then set up their own laboratory at Station Avenue, Kew Gardens. In 1888, the first edition of their joint publication A Textbook of Paper-making, appeared. It went into several editions and became the standard reference and textbook on the subject. The long introductory chapter is a discourse on cellulose.In 1892, Cross, Bevan and Clayton Beadle took out their historic patent on the solution and regeneration of cellulose. The modern artificial-fibre industry stems from this patent. They made their discovery at New Court, Carey Street, London: wood-pulp (or another cheap form of cellulose) was dissolved in a mixture of carbon disulphide and aqueous alkali to produce sodium xanthate. After maturing, it was squirted through fine holes into dilute acid, which set the liquid to give spinnable fibres of "viscose". However, it was many years before the process became a commercial operation, partly because the use of a natural raw material such as wood involved variations in chemical content and each batch might react differently. At first it was thought that viscose might be suitable for incandescent lamp filaments, and C.H.Stearn, a collaborator with Cross, continued to investigate this possibility, but the sheen on the fibres suggested that viscose might be made into artificial silk. The original Viscose Spinning Syndicate was formed in 1894 and a place was rented at Erith in Kent. However, it was not until some skeins of artificial silk (a term to which Cross himself objected) were displayed in Paris that textile manufacturers began to take an interest in it. It was then that Courtaulds decided to investigate this new fibre, although it was not until 1904 that they bought the English patents and developed the first artificial silk that was later called "rayon". Cross was also concerned with the development of viscose films and of cellulose acetate, which became a rival to rayon in the form of "Celanese". He retained his interest in the paper industry and in publishing, in 1895 again collaborating with Bevan and publishing a book on Cellulose and other technical articles. He was a cultured man and a good musician. He was elected a Fellow of the Royal Society in 1917.[br]Principal Honours and DistinctionsFRS 1917.Bibliography1888, with E.J.Bevan, A Text-book of Papermaking. 1892, British patent no. 8,700 (cellulose).Further ReadingObituary Notices of the Royal Society, 1935, London. Obituary, 1935, Journal of the Chemical Society 1,337. Chambers Concise Dictionary of Scientists, 1989, Cambridge.Edwin J.Beer, 1962–3, "The birth of viscose rayon", Transactions of the Newcomen Society 35 (an account of the problems of developing viscose rayon; Beer worked under Cross in the Kew laboratories).C.Singer (ed.), 1978, A History of Technology, Vol. VI, Oxford: Clarendon Press.RLHBiographical history of technology > Cross, Charles Frederick
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